What do you know and what are you trying to find?
Do you know the value of λand you're trying to find the X values? If so, build your coefficient matrix and right-hand side vector and use the backslash operator (\) to solve the system. Both the coefficient matrix and right-hand side will include λ. See the documentation page for the mldivide function for more information.
Do you know the values of X and you're trying to find λ? If so, you could use fzero on one of the equations that involve λ.
Do you know neither λ nor the values of X and you're trying to find all five? In this case you don't have a linear system, you have a nonlinear system (due to the λ*X1 and λ*X3 terms) and so you'd need to use something like fsolve from Optimization Toolbox.